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Over the last 15 years, the mothers' caravans have managed to locate 310 missing persons.
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"Migration-related detention for children can never be considered... in the best interest of the child. There are always alternatives available," he added.
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As a result of the meeting, the "Mexico Declaration" was issued in which the member countries of the Mechanism highlighted the need for a peaceful solution in Venezuela.
The president congratulated the Foreign and Defense secretaries for the successful operation of transporting former president Evo Morales from Bolivia, where his life was in danger, to Mexican soil
On Wednesday, Salvatierra said she is willing to install the parliamentary session and assume the presidency of the Plurinational State of Bolivia.
"It hurts to leave the country for political reasons... Soon I will return with more strength and energy,” Morales tweeted.
Russia, China, Uruguay and Argentina also expressed support for Evo Morales.
The Mexican foreign minister will demand an emergency meeting of the Organization of American States which he accused to remain silent after the "military pronouncement and police operations".
Argentina's President-elect Alberto Fernandez will host this historic meeting in Buenos Aires.
Two relatives Alex and Julian LeBaron told Reuters nine people had died, though a government source only confirmed five.
The two presidents are due to meet for talks later on Monday.
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